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Selasa, 12 Januari 2016

What To Consider When Choosing The Diffusion Coatings

By Dennis Campbell


Semiconductors and PV manufacturers are faced with significant corrosion challenges. They target to produce metallic components that can withstand extreme conditions such as varying pH levels, extremely high and low temperature, high pressure, and exposure to different environmental elements that significantly affects their physical properties. More often, the solution often involves diffusion coatings to give the base metal physiochemical and structural properties making them suitable to operate under extreme physical conditions.

The most common coating materials include silicon, aluminum, and chromium. These materials are used to offer a protective coating for metals such as cobalt, titanium, nickel alloys, iron and iron alloys like stainless steel and carbon. This enables the base material to develop a high resistance level against oxidation, erosion and corrosion even in extreme working conditions.

The top alloys used in coatings include steel, aluminum, titanium and chromium. Silicon is also widely used, but not as alloys. The properties of these metallic materials include the ability to withstand high temperature, extreme pH levels, and high-pressure fluid in velocity. They form a protective outer coat used to protect iron materials, stainless steel, cobalt, nickel, carbon and several other metals.

As a result, the base metal becomes highly resistant to erosion, oxidation, and corrosion of up to 2100 degrees Fahrenheit without spallation. This high level of reliability makes it a critical stage for metals that are to be part of a system operating in extreme conditions of temperature, pressure, and physical conditions. The metal exposed to this process gets extraordinary physiochemical and mechanical properties previously unavailable.

However, not every coat works in the same way under the same conditions. Silicon has different properties from aluminum under the same conditions. As such, depending on the environment on which the base metal will be exposed, there are factors to consider when selecting the right coating material. Most alloys tend to leach metal ions which affect the process yield; however, silicon does not leach and has higher corrosion resistance properties. It is appropriate for highly sensitive processes.

To begin with, compatibility ranks high in the list of considerations when selecting the right diffusion coating material. No single metal alloy or compound can offer full protection against all forms of corrosive elements. However, the operation environment is also unlikely to expose the metal to all extreme conditions, as such; the wise option involves making the selection basing on the most likely condition of the process.

Whether the operating environment includes fluids that are basic or acidic, you have to go the extra mile to consider the concentration of the fluids. High concentration level translates to a high rate of corrosion and vice versa. Other factors like fluid velocity and the fluid type also affect the rate of corrosion.

The rate of erosion and corrosion also increases with the time of exposure. In some cases, the exposure is cyclical involving periodic wetting and drying of the metal surface without rinsing. This increases the corrosion rate significantly.

If the fluid is acid or basic, then the pH level makes a whole difference. Silicon coated metal last longer even in extremely acidic condition (low pH) and corrode faster in high pH (environment). The metals like aluminum and steel are corroded faster as long as the pH levels are extreme.




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